Mexico have been one of the biggest attractions of this World Cup.
Shin said he had assumed in his planning that Germany would have already qualified by the time this fixture came around and the fact that the world champions still need a win would make them a much more hard proposition.
Mueller was relegated to the bench after drawing a blank in Germany's first two matches in Russian Federation. If they continue to play well the result will come.
Videos posted on social media also showed ambassador Kim Sang-il sharing a bottle of tequila with fans and jumping up and down as the crowd partied outside the embassy, chanting "Korean brother, now you're Mexican!"
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The players can listen to the manager - and they should also be able to express themselves about what they do not like from him. The use of animals to forecast winners at the World Cup is a fairly recent fad.
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The president of the German Football Association (DFB) expects there to be changes in the squad after the tournament in Russian Federation but insists Loew, 58, will oversee the grooming of the next generation.
South Korea needed to beat Germany and then have Mexico defeat Sweden to have a chance of advancing from the group stage.
South Korea itself was eliminated.
South Korea coach Shin Tae-yong did not reveal which player would captain his side against Germany, just saying the role would not be for the faint-hearted.
After the game, coach Joachim Low refused to lay blame exclusively on Ozil. "It shows that with Italy and the Netherlands out before the tournament, Chile, who were in the Confederations Cup final, and now Germany, you can not relax and miss the opportunity to constantly improve". Portugal's campaign in Brazil unravelled four years ago after a heavy loss against Germany in the opening match. "We are very grateful", said Pablo Gonzalez, 45.
The German coach said all other players are available, including playmaker Mesut Ozil and midfielder Sami Khedira, who were dropped from the starting lineup against Sweden.